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Fluorine (F) is the chemical element with atomic number 9. It is the lightest halogen.Fluorine is a pale yellow gas composed of diatomic molecules, F2. Fluorine is the most electronegative element and is extremely reactive, requiring great care in handling. It has a single stable isotope, fluorine-19.

Fluorine reacts with practically all organic and inorganic substances. Finely divided metals, glass, ceramics, carbon, and even water burn in fluorine with a bright flame. It is not uncommon to see fluorine spelled incorrectly as flourine.Fluorine is available commercially in cylinders but is very difficult to handle. Fluorine may be recovered with difficulty as a highly reactive and corrosive pale yellow gas by electrolysis of hot molten mixtures (1:2) of potassium fluoride (KF) and hydrogen fluoride (HF). The electrolyte is corrosive, so is the product. Grease must be avoided because of the fire hazard. It is difficult to store as it reacts with most materials but steel and Monel metal containers may be used as the metal surfaces deactivate through the formation of unreactive surface fluorides.



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